Publication in Science: Electrically switchable metallic polymer plasmonic nanoantennas

October 27, 2021 /

Researchers develop electrically switchable nanoantennas as basis for holographic video technology

Video conferencing played a key role during the Covid-19 pandemic and is set to dominate many meetings in the future. To realize the true feeling of a face-to-face dialog, three dimensional video is required and yet the holographic technology is still missing. Researchers at the University of Stuttgart in Germany have now introduced a completely new approach to realize such dynamic holographic displays, based on electrically switchable plasmonic nanoantennas made from conductive metallic polymers. This key element provides the missing technology to enable holographic displays at video rate, which would enable virtual conferences with a “real-life” feeling. The paper detailing this work has been published in the leading journal Science on 29 October 2021.

Virtual meeting in the future: The conference member on the right is wearing VR/AR goggles, which display a hologram of the lady on the left.
Virtual meeting in the future: The conference member on the right is wearing VR/AR goggles, which display a hologram of the lady on the left.

stadt-bremerhaven.de Article

Holograms creating impressive three-dimensional static images are well known. Dynamic holograms switchable at video rates using data from a high-speed internet connection are not possible until now. Previously, the limiting factor was the display resolution. Holographic images require a resolution of 50 000 dpi (pixels per inch) which is 100x more than the best smartphone displays. For such a resolution one has to reduce the pixel size to half a micrometer (one thousands of a millimeter). However, current liquid-crystal technology does not allow for such small pixels, being limited to a few micrometers pixel size.

Researchers at the University of Stuttgart have succeeded in breaking this fundamental barrier. In an interdisciplinary collaboration between Physics and Chemistry, they developed the idea to use electrically switchable plasmonic nanoantennas with dimensions of only a few hundred nanometers and made from conductive polymers.

Scitechdaily Article

Conductive functional polymers as suitable switchable material

For several years, researchers had created metasurfaces that generate static 3-dimensional holograms. However, their components, or nanoantennas, consisted of metals such as gold or aluminum that could not be switched like common liquid crystal materials. After searching for several years for the right material, PhD student Julian Karst and nanophotonics expert Dr. Mario Hentschel from the group of Prof. Harald Giessen, together with polymer chemist Prof. Sabine Ludwigs and her team, identified electrically conducting polymers as possible candidates for switchable plasmonics. Sabine Ludwigs contributed her expertise on electrochemical switching of such functional polymers, that were at the focus of the 2000 Chemistry Nobel Prize.

Until now such materials had mostly been used for current transport in flexible displays and solar cells. In collaboration with cleanroom head Monika Ubl, Karst and Hentschel developed a process to nanostructure the metallic polymers using a combination of electron beam lithography and etching, thereby creating the plasmonic nanoantennas. The team showed that the optical appearance of the nanoantennas could be switched between that of a shiny metal and a transparent material by applying a voltage between minus and plus one volt. This switching effect works even at video rates of 30 Hertz. Despite being only a few tens of nanometers thick and less than 400 nanometers in size, the nanoantennas do the same job as the much larger and thicker liquid crystals used in current state-of-the-art technology. These new devices reach the required pixel densities of about 50.000 dpi.

Image symbolizing electrically switchable nanoantennas. The part of the nanoantenna with the lightning from top looks metallic, with metallic luster when it is electrically charged.
Image symbolizing electrically switchable nanoantennas. The part of the nanoantenna with the lightning from top looks metallic, with metallic luster when it is electrically charged.

hartware.de Article

Karst created a simple hologram metasurface from the nanoantennas that could deflect an infrared laser beam 10 degrees onto one side by applying a voltage. Currently, he is working on making this deflection available for many angles for applications in LIDAR devices in autonomous vehicles, of keen interest to the automotive industry. Additionally, Karst created a hologram that behaves like an optical lens, which can be turned on and off by simply applying ±1 Volt. This technology is crucial for future smartphone cameras or optical sensors that could be zoomed from wide angle to telephoto by switching the applied voltage. Currently, up to four lenses are required for this functionality.

In the future, Prof. Harald Giessen and his team aim to address every single pixel individually, to dynamically change the holograms at will at video rates. Also, the optical properties of the polymer nanoantennas have to be shifted into the visible wavelength range, which requires collaborations with chemists and material scientists. Together with engineers, integrated and dynamically switchable optical displays and the first moving holograms could be integrated into AR/VR goggles and eventually onto smartphone screens and even televisions.

Taking Moore’s law for display technology, this advance by about a factor of 100 could happen commercially around the year 2035.

(left): Image displaying the plasmonic polymer nanoantenna, switched into the dielectric (glassy) state. The light beam from the bottom just passes through to the top without being deflected. (right): Image displaying the plasmonic polymer nanoantenna, switched into the metallic state. The light beam from the bottom is deflected to the side when passing through the sample. The light also changes its handedness (see the different rotation direction of the spiraling light) when travelling to the top.

Chemie.de Article

(top): Image displaying the metallic polymer metasurface in order to obtain the beam steering functionality. (bottom): Scanning electron microscope (SEM) image of the metallic polymer metasurface that can be used for electric nanoantenna switching.
00:17

The movie shows on the bottom x-axis the applied voltage and on the y-axis the current flowing. This is called a cyclic voltammogram. On top the image of the video camera is displayed. As time goes on, the voltage is cycled back and forth and the diffracted light beam on the right side of the camera image is switched on and off. The movie is running in real time. Switching times as short as 30 milliseconds are possible.

Radio Interview with Deutschlandradio

Original Publication

Julian Karst et al., "Electrically switchable metallic polymer nanoantennas," Science 374, 612 (2021). https://www.science.org/doi/10.1126/science.abj3433

Scientific contact:

Prof. Dr. Harald Giessen, University of Stuttgart, Physics 4,  Tel.: +49 (0)711 6856 5111, E-Mail: giessen@physik.uni-stuttgart.de

Julian Karst, University of Stuttgart, Physics 4, Tel.: +49 (0)711 6856 4955, E-Mail: j.karst@pi4.uni-stuttgart.de

Media contact:

Andrea Mayer-Grenu, University of Stuttgart, University Communications, Phone : +49 (0)711/685 82176, E-Mail: andrea.mayer-grenu@hkom.uni-stuttgart.de

 

Download of above Images in High Resolution

This image shows Harald Giessen

Harald Giessen

Prof. Dr.

Director

This image shows Mario Hentschel

Mario Hentschel

Dr.

Head of Cleanroom and Nanostructuring Facilities

This image shows Julian Karst

Julian Karst

Dr.

Phase transition materials

To the top of the page